Product ID:POLYMERIC MDI INSTAPAK COMPONENT A
MSDS Date:01/01/1996
FSC:9330
NIIN:00N022813
MSDS Number: CCSZK

SEALED AIR CORP

10 OLD SHERMAN TURNPIKE
DANBURY, CT 06810
US

Emergency Phone: 203-791-3500;800-424-9300(CHEMTREC)

Info Phone: 203-791-3500

Cage: 51614

SEALED AIR CORP INSTAPAK DIVISION

DANBURY, CT 06810 US

Telephone: 203-791-3500/800-424-9300(CHEMTREC)

Cage: 51614

NITRILE RUBBER, POLYVINYL ALCOHOL, OR OTHER

RTECS: 9999999ZZ

USE AND HANDLING OF INSTAPAK

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OXYGEN CAN BE ASSURED. WHERE CONCENTRATIONS EXCEED

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IN A

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AEROSOLS FOR 6 HRS/DAY, 5 DAYS/WK FOR LIFETIME. RATS

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5 TIMES OSHA PEL (1 MG/M3), & AT 30 TIMES OSHA PEL

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PEL, WAS THERE A STATISTICALLY RECOGNIZABLE NUMBER

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LUNG IRRIT & ACCUM OF YELLOW MATL IN LUNGS WAS SEEN

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LESSER DEGREE IN GROUP EXPOSED AT 5 TIMES OSHA PEL.

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TUMOR FORMATION WILL RESULT FROM EXPOSURES AT OR

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DRINK WATER TO REDUCE CORROSIVITY. CONSULT

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ALLOW TO STAND UNCOVERED FOR 48-72 HRS. WASH

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WORN DURING SPILL CLEANUP & VENT MAINTAINED. IF THE

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THE PEL EXISTS, THEN NIOSH APPROVED RESPIRATORY

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INDICATORS, CARTRIDGE TYPE RESPS EQUIPPED FOR

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THEY CAN BE USED FOR SHORT TERM EMER SITUATIONS AT

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OTHER MDI ISOMERS AND OLIGOMERS

OSHA PEL N/K

ACGIH TLV: N/K

POLYMETHYLENE POLYPHENYLENE POLYISOCYANATE; (ISOCYANIC

CAS: 9016-87-9

RTECS: TR0350000

Fraction By Weight: 100%

OSHA PEL N/K

ACGIH TLV: N/K

MDI)) CONTAINING INGREDIENTS 3 AND 4

RTECS: 9999999ZZ

ISOCYANIC ACID, METHYLENEDI-P-PHENYLENE ESTER;

CAS: 101-68-8

RTECS: NQ9350000

Fraction By Weight: 45%

OSHA PEL C 0.02 PPM

ACGIH TLV: 0.005 PPM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

LD50 LC50 Mixture:LD50 (ORAL RAT): 20 G/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:DUE TO LOW VAP PRESS, OVEREXP IS NOT
EXPECTED UNDER NORM CNDTNS UNLESS MATL IS HEATED/USED IN POORLY
VENTD AREA. ACUTE: INHAL: MAY LEAD TO MUC MEMB IRRIT, TIGHTENING OF
CHEST, RESP TRACT IRRIT, COUGHI NG, HDCH, SHORTNESS OF BRTH. MAY
LEAD TO ALLERGIC SENSITIVITY IN SOME INDIVIDUALS RESULTING IN (EFTS
OF OVEREXPOSURE)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: ASTHMA-LIKE SYMPS UPON EXPOS BELOW
PEL. SENSITIZED PERS SHOULD BE REMOVED FROM ANY FURTHER EXPOS.
SKIN: MAY CAUSE IRRIT/RASH. CAN CAUSE SKIN DISCOLORATION. RPTD CONT
MAY RSLT IN SKIN SENSIT. LAB TESTS HAVE INDICATED THAT RESP SENSIT
CAN RSLT FROM SKIN CONT W/MDI. THIS DATA REINFORCES NEED TO PVNT
(SUP DAT)
Medical Cond Aggravated by Exposure:PULMONARY DISORDERS. PERSONS WITH
ASTHMA-TYPE CONDITIONS OR OTHER CHRONIC RESPIRATORY DISEASES SHOULD
BE EXCLUDED FROM WORKING WITH MDI.

First Aid:INHAL: REMOVE TO UNCONTAM AREA, ADMIN OXYGEN IF NEC.
ASTHMATIC-LIKE SYMPS, IF MANIFESTED, MAY DEVELOP IMMED/BE DELAYED
FOR UP TO SEVERAL HRS. OBTAIN MED ATTN. TREATMENT IS SYMTPMATIC.
SKIN: WASH AREA THORO W/SOAP & WATER. LAUNDER CONTAM CLTHG BEFORE
REUSE. EYE: FLUSH W/COPIOUS AMTS OF WATER FOR AT LEAST 15 MIN,
HOLDING LIDS OPEN W/FINGERS. CONSULT MD. INGEST: DO NOT INDUCE
VOMIT. (ING 12)

Flash Point Method:PMCC
Flash Point:390F,199C
Extinguishing Media:CARBON DIOXIDE, CHEMICAL FOAM, DRY CHEMICAL, WATER
SPRAY.
Fire Fighting Procedures:WEAR NIOSH APPRVD SCBA & FULL PROT EQUIP .
AVOID WATER CONTAM IN CLSD CONTRS; CARBON DIOXIDE IS EVOLVED WHICH
CAN CAUSE PRESS BUILD-UP. (SUP DAT)
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.

Spill Release Procedures:SPILL SHOULD BE COVERED W/LOOSE ABSORB/ABSORB
PILLOWS, PADS/SOCKS. POUR DEACTIVATING SOLN (90% WATER, 8% CONC
AMMONIA, 2% DETERGENT) OVER SPILL AREA; ALLOW TO REACT 10
MIN/LONGER. COLLECT MATL IN OPEN CONTRS & TREAT W/ADDNL
DEACTIVATING SOLN;(ING 13)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STOR TEMP: MIN 50F (10C), MAX 100F
(38C). AVERAGE SHELF LIFE: 6 MONTHS. REACTS WITH MOISTURE TO
PRODUCE CARBON DIOXIDE GAS.
Other Precautions:DO NOT STORE DRUMS UNCOVERED OUT OF DOORS. DO NOT
RESEAL CONTAINERS UNLESS IT IS CERTAIN THAT NO MOISTURE
CONTAMINATION HAS OCCURRED. DO NOT BREATHE VAPORS OR ALLOW SKIN
CONTACT.

Respiratory Protection:DUE TO THE LOW VAP PRESS OF THIS MATL, PEL IS
NOT LIKELY TO BE EXCEEDED UNDER NORM CNDTNS. IF THE MATL IS
HEATED/SPILLED IN CONFINED AREA, NIOSH APPRVD RESP PROT SHOULD BE
WORN. BECAUSE OF THEIR SHORT LIFE & LACK OF BREAKTHROUGH (ING 16)
Ventilation:USE LOCAL EXHAUST IF NECESSARY TO MAINTAIN LEVELS BELOW THE
PEL.
Protective Gloves:CHEM RESISTANT BUTYL RUBBER, (ING 19)
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA . SEE "RECOMMENDATIONS FOR THE SAFE (ING 20)
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC: CAUTION: RXN BETWEEN WATER & HOT ISOCYANATE CAN BE
VIGOROUS. EFTS OF OVEREXP: DIRECT SKIN CONT. EYE: LIQ CAN CAUSE
IRRIT, TEARING, REDDENING & SWELL. PERM CORNEAL INJURY IS UNLIKELY.
IN ADDN, VAPS IN EXCESS OF 0.02 PPM MAYCAUSE IRRIT. INGEST: INGEST
IS UNLIKELY. CAN CAUSE IRRIT & CORR ACTION (ING 5)

Boiling Pt:B.P. Text:625F,329C
Vapor Pres:<10-5 @25C
Vapor Density:8.5
Spec Gravity:1.24
Solubility in Water:REACTS WITH WATER
Appearance and Odor:DARK BROWN LIQUID, SLIGHTLY AROMATIC ODOR
Percent Volatiles by Volume:NIL

Stability Indicator/Materials to Avoid:YES
WATER, AMINES, STRONG BASES AND ALCOHOLS.
Stability Condition to Avoid:AVOID TEMPS ABOVE 110F (43C) OR BELOW 40F
(4C). CONTACT WITH MOISTURE & OTHER MATERIALS WHICH CONTAN ACTIVE
HYDROGEN.
Hazardous Decomposition Products:BY FIRE OR EXTREME HEAT: OXIDES OF
CARBON, OXIDES OF NITROGEN, TRACES OF HYDROGEN CYANIDE.
Conditions to Avoid Polymerization:ELEVATED TEMPERATURES.

Waste Disposal Methods:INCINERATE/DISPOSE OF IN ACCORDANCE W/EXISTING
FEDERAL, STATE AND LOCAL ENVIRONMENTAL CONTROL REGULATIONS. ALSO
SEE "RECOMMENDATIONS FOR THE SAFE USE AND HANDLING OF INSTAPAK
FOAM-IN-PLACE CHEMICALS" BULLETIN & OTHER REGULATORY
INFORMATIONSECTION.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.